io9 has a list of 20 scientific books that they think science fiction fans should read:
What are the science books you should be reading now if you want your brain turned inside-out by weird new ideas that might just change the world for real? We’ve got 20 brilliant, and brilliantly-written, science books that have already influenced science fiction — or are about to.
For the record, I’ve read only four of these, though I’ve been meaning to borrow the Feynman from my father, who is a fan. Note that they are definitely not all “hard science.” I may look into a few more. And the robot one looks like just prudent reading.
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